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71.
72.
三峡库区悬移质泥沙对磷污染物的吸附解吸特性 总被引:3,自引:0,他引:3
就三峡库区悬移质泥沙对磷污染物的吸附解吸特性从野外同步监测和室内试验研究两个方面展开研究。选取长江干流、嘉陵江和乌江共7个监测断面于2002年和2003进行野外同步监测,测试结果表明:水中的悬移质泥沙对水中各种覆存形态的磷污染物浓度具有显著影响,单位重量泥沙对磷的吸附量与水体总泥沙含量、泥沙粒径有密切关系。采集寸滩断面泥沙对磷酸盐吸附解吸特性进行室内试验研究,并根据Langmuir吸附动力学方程对吸附解吸过程进行了拟合,发现吸附速率常数k随着泥沙粒径的增加而呈递增变化,而磷酸盐初始浓度对k值的影响并不明显,同时,磷酸盐解吸量随着泥沙浓度的增加和粒径的增加呈递减变化,k值随着泥沙粒径的增加而呈递增变化,泥沙浓度对k值的影响不明显。 相似文献
73.
CFD技术在水处理紫外消毒中的应用 总被引:1,自引:0,他引:1
介绍了紫外消毒在水处理中应用的现状,阐述了计算流体力学(CFD)的基本原理及其应用背景;论述了CFD技术在紫外消毒模型建立方面的关键因素:水力、辐射和剂量模拟;从消毒效率预测和设备结构优化两个方面对CFD技术在水处理紫外消毒中的应用进行了分析,并对其前景进行了展望,提出了今后的研究重点。 相似文献
74.
Yusheng Wang Zhiguo Pei Xiaoquan Shan Guangcai Chen Jing Zhang Yaning Xie Lirong Zheng 《环境科学学报(英文版)》2011,23(1):112-118
The mutual e ects of metal cations (Cu2+, Pb2+, Zn2+, and Cd2+) and p-nitrophenol (NP) on their adsorption desorption behavior
onto wheat ash were studied. Results suggested that Cu2+, Pb2+, and Zn2+ diminished the adsorption and increased the desorption of
NP remarkably, while Cd2+ had no such e ect. In contrast, NP diminished the adsorption of Cu2+, Pb2+, and Zn2+ onto ash, however,
this suppression e ect depended on the initial concentrations of metal cations. NP had no e ect on Cd2+ adsorption on ash. Fourier
transform infrared (FT-IR) and X-ray absorption spectroscopic (XAS) studies suggested the following mechanisms responsible for the
metal suppression e ect on NP adsorption: (1) large hydrated Cu2+, Pb2+, and Zn2+ shells occupied the surface of ash and prevent
nonspecific adsorption of NP onto ash surface; (2) Cu2+, Pb2+, and Zn2+ may block the micropores of ash, resulting in decreased
adsorption of NP; (3) complexation of Cu2+, Pb2+, and Zn2+ was likely via carboxyl, hydroxylic and phenolic groups of wheat ash and
these same groups may also react with NP during adsorption. As a “soft acid”, Cd2+ is less e cient in the complexation of oxygencontaining
acid groups than Cu2+, Pb2+, and Zn2+. Thus, Cd2+ had no e ect on the adsorption of NP on wheat ash. 相似文献
75.
The Hg0 vapor adsorption experimental results on a novel sorbent obtained by impregnating a commercially available activated
carbon (Darco G60 from BDH) with silver nitrate were reported. The study was performed by using a fundamental approach, in an
apparatus at laboratory scale in which a synthetic flue gas, formed by Hg0 vapors in a nitrogen gas stream, at a given temperature
and mercury concentration, was flowed through a fixed bed of adsorbent material. Breakthrough curves and adsorption isotherms were
obtained for bed temperatures of 90, 120 and 150°C and for Hg0 concentrations in the gas varying in the range of 0.8–5.0 mg/m3. The
experimental gas-solid equilibrium data were used to evaluate the Langmuir parameters and the heat of adsorption. The experimental
results showed that silver impregnated carbon was very effective to capture elemental mercury and the amount of mercury adsorbed by
the carbon decreased as the bed temperature increased. In addition, to evaluate the possibility of adsorbent recovery, desorption was
also studied. Desorption runs showed that both the adsorbing material and the mercury could be easily recovered, since at the end of
desorption the residue on solid was almost negligible. The material balance on mercury and the constitutive equations of the adsorption
phenomenon were integrated, leading to the evaluation of only one kinetic parameter which fits well both the experimentally determined
breakthrough and desorption curves. 相似文献
76.
The study investigated the effects of ethanol on the adsorption properties of bentonite and kaolin for benzene and toluene removal. 相似文献
77.
Harish Venkatakrishnan Youming Tan Maszenan bin Abdul Maji Santosh Pathak Antonius Yudi Sendjaj Dongzhe Li Jerry Jian Lin Liu Yan Zhou Wun Jern Ng 《环境科学学报(英文版)》2014,26(4):875-884
A high strength chemical industry wastewater was assessed for its impact on anaerobic microbial com- munity dynamics and consequently mesophilic methane generation. Cumulative methane production was 251 mL/g total chemical oxygen demand removed at standard temperature and pressure at the end of 30 days experimental period with a highest recorded methane percentage of 80.6% of total biogas volume. Volatile fatty acids (VFAs) analysis revealed that acetic acid was the major intermediate VFAs produced with propionic acid accumulating over the experimental period. Quantitative analysis of microbial communities in the test and control groups with quantitative real time polymerase chain reaction highlighted that in the test group, Eubacteria (96.3%) was dominant in comparison with methanogens (3.7%). The latter were dominated by Methanomicrobiales and Methanobacteriales while in test groups increased over the experimental period, reaching a maximum on day 30. Denaturing gradient gel electrophoresis profile was performed, targeting the 16S rRNA gene of Eubacteria and Archaea, with the DNA samples extracted at 3 different time points from the test groups. A phylogenetic tree was constructed for the sequences using the neighborhood joining method. The analysis revealed that the presence of organisms resembling Syntrophomonadaceae could have contributed to increased production of acetic and propionic acid intermediates while decrease of organisms resembling Pelotomaculum sp. could have most likely contributed to accumulation of propionic acid. This study suggested that the degradation of organic components within the high strength industrial wastewater is closely linked with the activity of certain niche microbial communities within eubacteria and methanogens. 相似文献
78.
研究应用电阻加热强化气相抽提技术对砂土、壤土和黏土中苯去除效果的影响及作用机制.与常规抽提结果相比,在热强化处理作用下气相抽提对砂土和壤土中苯的去除效率提高了13.1%和12.3%,处理时间分别降低75%和14%.热强化处理使得黏土含水率下降,土壤渗透率升高,黏土颗粒表面羧基和乙基的吸收峰消失,有机质含量减少,苯的去除效率与对照相比提高了34%.对于砂土和壤土,热强化主要是通过促进苯在土体中扩散来提高去除效率,从而实现在较短时间内污染物质的大量去除;而对于黏土则是通过降低土壤颗粒表面有机基团的含量,从而降低污染物和土壤颗粒的吸附能力,并通过降低含水率和升高渗透率从而提高土壤中气体的扩散性能,以达到增强气相抽提效果的目的. 相似文献
79.
80.
采用大涡模型对L形和U形三维钝体建筑物的绕流特性和风压分布特性进行数值研究.考虑平均和脉动速度入口边界,在雷诺数为1.5×105~7×105条件下,对2种钝体的9种分析工况进行瞬态动力分析,并将计算结果与已有研究进行对比.研究表明,钝体绕流对周围流场影响的强弱程度依次为尾流区、屋顶区、来流区,影响大小随着流场与钝体之间... 相似文献